In terms of academic and co-curricular activities the school is one of the performing schools in Albay Division.

The school through a dynamic, efficient and empowered leader, relevant and responsive curricula delivered by a team component, efficient, effective, and morally upright teachers with multiple partnerships with parents, various government groups and other stakeholders produce students who are equipped with basic knowledge, skill and values that enable them to become fruitful citizens ready to adapt to the modernized society and advanced technology in acing the world of works.

Naga National High School had offered the following curricula in the secondary level : The General Secondary Education Curriculum or known as the Revised Basic Education Curriculum (RBEC),2010 SEC, K+12, and the Engineering Science Education Curriculum (ESEP). The very purpose of this curriculum (ESEP) is to expose the students in the field of Science and Mathematics. The school also signed a memorandum of agreement on the integration of the Geothermal Education and Climate Change Adaptation in teaching across the curriculum as the pioneer in Bicol. In terms of academic and co-curricular activities the school is one of the performing schools in Albay Division.